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Title: | Bis[(2-quinol-yl)methane-diol-κN,O](sulfato-κO)copper(II) dihydrate | Authors: | Martins, Nuno D. Silva, Joana A. Silva, Manuela Ramos Beja, Ana Matos Sobral, Abílio J. F. N. |
Keywords: | single-crystal X-ray study; T = 293 K; mean (C–C) = 0.004 A°; R factor = 0.038; wR factor = 0.091; data-to-parameter ratio = 16.0 | Issue Date: | 23-Jan-2008 | Publisher: | International Union of Crystallography | Project: | POCI/FIS/57876/2004 | metadata.degois.publication.title: | Acta Crystallographica Section E: Structure Reports Online | metadata.degois.publication.volume: | 64 | metadata.degois.publication.issue: | Pt 2 | Abstract: | In the title compound, [Cu(SO(4))(C(10)H(9)NO(2))(2)]·2H(2)O, the Cu(II) ion is chelated by two (2-quinol-yl)methane-diol ligands and coordinated by a monodentate sulfate ligand in a distorted trigonal-bipyramidal environment, with O atoms occupying the equatorial sites and N atoms in the axial sites. The dihedral angle between the two essentially planar quinoline ring systems is 45.02 (9)°. In the crystal structure, an extensive O-H⋯O hydrogen-bonding network forms layers parallel to the ab plane. | URI: | https://hdl.handle.net/10316/110438 | ISSN: | 1600-5368 | DOI: | 10.1107/S1600536808001980 | Rights: | openAccess |
Appears in Collections: | FCTUC Química - Artigos em Revistas Internacionais FCTUC Física - Artigos em Revistas Internacionais |
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Bis2quinolylmethanediolsup2sup-NOsulfatoO-copperII-dihydrateActa-Crystallographica-Section-E-Structure-Reports-Online.pdf | 578.79 kB | Adobe PDF | View/Open |
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